Semiconductor-catalyzed photooxygenation of aromatic olefins |
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| Authors: | Tatsuya Kanno Takahide Oguchi Hirochika Sakuragi Katsumi Tokumaru |
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| Institution: | Department of Chemistry, The University of Tsukuba, Sakura-mura, Ibaraki 305, Japan |
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| Abstract: | Irradiation of semiconductors (TiO2 and CdS) suspended in organic solvents containing 1,1-diphenylethylene and its derivatives under oxygen afforded the corresponding epoxides and benzophenone. A possible mechanism is discussed. |
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