Stepwise conversion of oxiranes to allylic alcohols by iodotrimethylsilane and DBU |
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| Authors: | Hideki Sakurai Koshi Sasaki Akira Hosomi |
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| Institution: | Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980, Japan |
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| Abstract: | Iodotrimethylsilane, prepared from hexamethyldisilane and iodine reacts smoothly with oxiranes to give (2-iodoalkoxy)trimethylsilanes which can be converted to allylic alcohols with DBU in good yields. The whole conversion can be carried out in one-pot operation. |
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