Nonplanarity of π systems. An ab initio study of norbornene and norbornadiene |
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| Authors: | G. Wipff K. Morokuma |
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| Affiliation: | Institut de Chimie, BP 296/R8, 67000 Strasbourg, France;Institute for Molecular Science, Myodaiji, Okazaki 444, Japan |
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| Abstract: | The geometry of norbornene and norbornadiene fully optimized by ab initio calculations reveals the nonplanarity of the π system(s). The exo addition of electrophiles on norbornene systems is analyzed in this context. |
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