Temperature dependence of the gas-phase reactions F+CHFO,CFO+F,and CFO+CFO |
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Authors: | Peter Behr Cornelia Kaupert Eduard Shafranovski Horst Heydtmann |
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Abstract: | The rate coefficients for the reactions CHFO+F, CFO+F and the self-reaction of CFO were determined over the temperature range of 222–298 K. A computer controlled discharge-flow system with mass spectrometric detection was used. The results are expressed in the Arrhenius form (with energies in J): CHFO+F→CFO+HF: k1(T)=(9.7±0.7)·10−12 exp[−(5940±150)/RT] cm3 molecule−1 s−1 CFO+F+M→CF2O+M: FORMULA DISC=“MATH”>k2(T)=(2.60±1.17)·10−10 exp[−(10110±1250)/RT cm3 molecule−1 s−1FORMULA CFO+CFO→CF2O+CO: k3(T)=(3.77±2.7)·10−10 exp[−(8350±2800)/RT] cm3 molecule−1 s−1 © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 329–333, 1998 |
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