Preparation of hexacoordinated tris(bidentate) phosphorus compounds with 1,3,2-dioxaphosphorinane rings. NMR and X-ray crystallographic studies of their conformation |
| |
Authors: | Skowronska Kowara Kaminski Bujacz Wieczorek |
| |
Institution: | Polish Academy of Sciences, Centre of Molecular and Macromolecular Studies, Department of Heteroorganic Chemistry, Sienkiewicza 112, 90-363 Lodz, Poland, and Technical University of Lodz, Institute of Technical Biochemistry, Stefanowskiego 4/10. |
| |
Abstract: | A series of new unstable tris(bidentate) hexacoordinated phosphorus compounds 1 with 1,3,2-dioxaphosphorinane rings was prepared and studied by NMR and X-ray crystallography. The X-ray crystal structures showed that the 1,3,2-dioxaphosphorinane ring adopts different conformations depending on the number and size of substituents at the carbon atom C14. Substituents are deployed around the phosphorus atom in a slightly deformed octahedral structure. Deviations in bond lengths around the phosphorus atom depend on the character of the bonds and the distribution of the negative charge. (1)H and (13)C NMR measurements showed that in solution the flexibility of 1,3,2-dioxaphosphorinane ring depends on the size of substituents at the carbon C14. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|