Formation of an unusual charge-transfer network from an ionic liquid |
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| Authors: | Del Sesto Rico E Baker Gary A Baker Sheila N Scott Brian L Keizer Timothy S Burrell Anthony K McCleskey T Mark |
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| Institution: | Structural and Inorganic Chemistry, Division of Chemistry, Los Alamos National Laboratory, NM 87545, USA. |
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| Abstract: | An intriguing and novel charge-transfer complex between dimethyldihydrophenazine and diethylviologen has been crystallized from an ionic liquid at room temperature, resulting in an interesting stacking motif of interrupted D***A***D type triads: efficient formation of the complex is seen within an ionic liquid and acetone, with the complex absorbing strongly across nearly the entire visible-NIR spectral region. |
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