| 双环[2.2.1]-2-庚烯-5，6-二甲酸镍配合物的合成、晶体结构及热稳定性 |
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| 引用本文： | 许金生,袁亚莉.双环[2.2.1]-2-庚烯-5，6-二甲酸镍配合物的合成、晶体结构及热稳定性[J].无机化学学报,2010,26(5):917-920. |
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| 作者姓名： | 许金生 袁亚莉 |
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| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,421008
2. 南华大学化学化工学院,衡阳,421001 |
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| 基金项目： | 湖南省重点建设学科项目，湖南省科技厅项目 |
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| 摘 要： | The nickel complex Ni(phen)(H2O)3C8H11O2(COO)] has been synthesized with bicycle2.2.1]hept-2-en-5,6-dicarboxylic acid C7H8(COOH)2] by means of solvent way. It crystallizes in the triclinic space group P1, with a=0.780 58(16) nm, b=1.189 9(2) nm, c=1.214 8(2) nm, α=66.20(3)°, β=88.28(3)°, γ=86.33(3)°, V=1.030 3(4) nm3, Dc=1.554 g·cm-3, Z=2, F(000)=502. Final GOF=1.107, R1=0.026 4, wR2=0.070 2. The crystal structure shows that the nickel ion is coordinated with four oxygen atoms from one bicycle2.2.1]-2-hepten-5,6-dicarboxylic acid molecule and three water molecules, respectively, with two nitrogen atoms from the 1,10-phenanthroline molecule, forming a distorted octahedral coordination geometry. The result of TG analysis shows that the title complex was stable under 210.0 ℃. CCDC: 741933.
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| 关 键 词： | 镍(Ⅱ)配合物 晶体结构 热重分析 |
Synthesis, Crystal Structure and Thermal Stability of Nickel Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid |
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| XU Jin-Sheng and YUAN Ya-Li.Synthesis, Crystal Structure and Thermal Stability of Nickel Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2010,26(5):917-920. |
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| Authors: | XU Jin-Sheng and YUAN Ya-Li |
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| Institution: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 and College of Chemistry and Chemical Engineering, Nanhua University, Hengyang, Hunan 421001 |
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| Abstract: | The nickel complex Ni(phen)(H2O)3C8H11O2(COO)]has been synthesized with bicycle2.2.1]hept-2-en-5,6-dicarboxylic acidC7H8(COOHh]by meanS of solvent way.It crystallizes in the triclinic space group P1,with a=0.78058(16)nm,b=1.1899(2)nm,c=1.2148(2)nm,α=66.20(3)°,β=88.28(3)°,γ=86.33(3)°,V=1.0303(4)nm3,Dc=1.554g·cm-3,Z=22,F(000)=502.Final Gof=1.107,R1=0.0264,wR2=0
0702.The crystal structure shows that the nickel ion is coordinated with four oxygen atoms from one bicycle2.2.1]-2-hepten-5,6-dicarboxylic acid molecule and three water molecules,respectively,with two nitrogen atoms from the 1,10-phenanthroline molecule,forming a distorted octahedral coordination geometry.The result of TG analysis shows that the title complex was stable under 210.0℃.CCDC:741933. |
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| Keywords: | crystal structure thermal stability analysis |
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