Synthesis and structural characterization of palladium(II) and platinum(II) complexes containing a chiral P,N-donor iminophosphine ligand |
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| Institution: | 1. Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas, Casilla 233, Santiago 1, Chile;2. Universidad de Santiago de Chile, Facultad de Química y Biología, Av. Libertador Bernardo O''Higgins 3363, Casilla 40, Correo 33, Santiago, Chile;3. Pontificia Universidad Católica de Valparaíso, Facultad de Ciencias, Avenida Universidad 330, Valparaíso, Chile;4. UMR 6226 CNRS-Université de Rennes 1, Sciences Chimiques de Rennes, Campus de Beaulieu, 35042 Rennes, France;1. Institute of Environmental Biotechnology, University of Natural Resources and Life Sciences Vienna, Konrad Lorenz Strasse 20, Tulln 3430, Austria;2. Sappi Papier Holding GmbH, Brucker Strasse 21, Gratkorn 8101, Austria;3. Graz University of Technology, Institute of Paper, Pulp and Fibre Technology, Inffeldgasse 23, Graz 8010, Austria |
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| Abstract: | A new chiral P,N-donor iminophosphine ligand was used to synthesize a series of palladium(II) and platinum(II) complexes. Single crystal X-ray analysis showed that in all cases the P,N ligand forms a six-membered chelate ring, and the square-planar coordination of the metal atom is completed by two halide ions, two methyl groups, or one methyl group and one halide ion. In the latter instance, the methyl group is cis to the phosphorus atom. |
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