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Synthesis of biomimetic light-driven molecular switches via a cyclopropyl ring-opening/nitrilium ion ring-closing tandem reaction |
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| Authors: | Vinicio Zanirato Gian P Pollini Filippo Valente Stefania Fusi Massimo Olivucci |
| Institution: | a Dipartimento di Scienze Farmaceutiche, Università di Ferrara, Via Fossato di Mortara 17-19, I-44100 Ferrara, Italy b Dipartimento di Chimica, Università di Siena, Via Aldo Moro 2, I-53100 Siena, Italy c Chemistry Department, Bowling Green State University, Bowling Green, 43403 OH, USA |
| Abstract: | A cyclopropyl ring-opening/nitrilium ion ring-closing tandem reaction has been conveniently used in an expeditious synthetic approach to light-driven Z/E molecular switches featuring an imine function conjugated to olefin groups that mimics natural protonated Schiff bases. |
| Keywords: | Light-driven molecular switches Tandem reaction Nitrilium ion cyclization Cyclopropylcarbinyl cation |
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