Towards the biosynthesis of the aromatic products of the Mediterranean mollusc Scaphander lignarius: isolation and synthesis of analogues of lignarenones |
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| Authors: | Giorgio Della Sala Angelo Fontana Aldo Spinella Gianpiero Calabrese Giuliana d'Ippolito Guido Cimino |
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| Institution: | a Università degli Studi di Salerno, Dipartimento di Chimica, Via Ponte Don Melillo, 84084 Fisciano, Salerno, Italy
b Istituto di Chimica Biomolecolare del CNR, Via Campi Flegrei 34, 80078 Pozzuoli (NA), Italy |
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| Abstract: | Secondary metabolites of the Mediterranean mollusc Scaphander lignarius from different collection sites have been investigated, proving the constant presence of a number of minor metabolites correlated to the already known lignarenones. Complete characterization of the new metabolites has been supported by enantioselective synthesis. The data are consistent with the origin of this unique class of ω-phenyloctanoids from a common polyketide pathway. |
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| Keywords: | Structure elucidation Stereochemistry Natural products Biosynthesis Chemical ecology |
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