The synthetic potential of graphite-catalyzed alkylation |
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| Authors: | Grigoriy A Sereda Vikul B Rajpara Ryan L Slaba |
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| Institution: | The University of South Dakota, Department of Chemistry, 414 E. Clark St., Vermillion, SD 57069, USA |
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| Abstract: | Unmodified graphite is introduced as a mild catalyst for alkylation of aromatic compounds and primary alcohols, applicable when utilization of strong Lewis acids is not feasible. The electrophilic intermediate has a significant carbocationic character and can be formed on a partially rate-limiting step. |
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