Synthesis of indole alkaloid analogues containing the novel hexahydropyrrolo[1′,2′,3′:1,9a,9]imidazo[1,2-a]indole skeleton by ring-closing reactions of tryptophan-derived α-amino nitriles |
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Authors: | Juan A González-Vera |
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Institution: | Instituto de Química Médica (CSIC), Juan de la Cierva 3, E-28006 Madrid, Spain |
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Abstract: | New indole alkaloid analogues, containing a 10b-methyl- or a 10b-hydroxy-1,2,4,5,10b,10c-hexahydropyrrolo1′,2′,3′:1,9a,9]imidazo1,2-a]indole skeleton, have been obtained by highly stereoselective electrophile addition-cyclization reactions of a tryptophan-derived α-amino nitriles. |
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