Gas-phase pyrolytic reaction of 3-anilino-1-propanol derivatives: kinetic and mechanistic study |
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Authors: | MR Ibrahim YA Ibrahim M Patel S Al-Awadi |
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Institution: | Chemistry Department, Kuwait University, PO Box 5969, Safat 13060, Kuwait |
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Abstract: | 3-Anilino-1-propanol derivatives 4a-c, 5a-c, 6a-c containing primary, secondary, and tertiary alcohols and PhNH, PhNMe, and (Ph)2N were prepared and subjected to gas-phase pyrolysis in a static reaction system. The pyrolytic reactions were homogeneous and followed a first-order rate equation. Reactions took place by retro-ene process, with the exception of compounds 5a and 5b. Analysis of the pyrolysate showed the products to be N-substituted aniline and carbonyl compounds. The kinetic results and product analysis of each of the nine investigated 3-amino alcohols are rationalized in terms of a plausible transition state for the elimination pathway. |
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Keywords: | 3-Anilino-1-propanol Pyrolysis Kinetics Reaction mechanism |
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