Rotational isomerism of some 1-substituted silatranes |
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| Authors: | O. A. Varnavskaya É. A. Ishmaeva V. M. D'yakov M. S. Sorokin M. G. Voronkov A. N. Pudovik |
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| Affiliation: | (1) V. I. Ul'yanov-Lenin Kazan State University and the Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions It was shown by the DM method that the   conformation of the side chain is realized in the 1--halo-propylsilatranes, the gauche form is realized predominantly in the 1-thioethoxymethylsilatranes, while a trans orientation of the C-S bond with respect to the silatrane fragment is realized in the 1- -thioethoxye-thylsilatranes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7. pp. 1671–1673, July, 1977. |
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