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Polycarbonates of bis(4-hydroxyphenyl)phenylmethane and bis(4-hydroxyphenyl)diphenylmethane
Affiliation:1. Department of Agriculture and Environmental Sciences, National Institute of Food Technology Entrepreneurship and Management, Sonepat, India;2. National Physical Laboratory, CSIR, New Delhi 110012, India;3. National Centre for Biological Sciences, Bengaluru, India;1. College of Environmental Sciences and Engineering, Peking University, The Key Laboratory of Water and Sediment Sciences, Ministry of Education, 100871, China;2. Center for Agricultural Water Research in China, China Agricultural University, Beijing 100083, China;3. School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States;4. Department of Environmental Science & Engineering, Fudan University, Shanghai, 200433, PR China;1. Department of Textiles, Ghent University, Technologiepark-Zwijnaarde 907, B-9052 Zwijnaarde, Belgium;2. Department of Materials Science and Engineering, Ghent University, Technologiepark-Zwijnaarde 903, B-9052 Zwijnaarde, Belgium;3. Department Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2, B-1050 Brussels, Belgium
Abstract:The polycarbonates prepared by phosgenation of bis(4-hydroxyphenyl)phenylmethane (BHPM) or bis(4-hydroxyphenyl)diphenylmethane (BHDM) were characterized by inherent viscosity measurements, infra-red spectroscopy, differential scanning calorimetry and thermogravimetric analysis. The polycarbonate of BHDM showed a significantly higher glass transition temperature as well as polymer decomposition temperature than the BHPM polycarbonate. Several physical and thermal characteristics of these polymers were correlated with their chemical structure.
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