Direct and selective benzylic oxidation of alkylarenes via C-H abstraction using alkali metal bromides |
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| Authors: | Moriyama Katsuhiko Takemura Misato Togo Hideo |
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| Institution: | Graduate School of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522, Japan. moriyama@faculty.chiba-u.jp |
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| Abstract: | A direct benzylic oxidation of alkylarenes via C-H bond abstraction was developed using alkali metal bromides and oxidants under mild conditions. This reaction proceeded with excellent selectivity by thermal oxidation or photooxidation to provide a broad range of carbonyl compounds containing electron-deficient aryl carbonyl compounds in high yields. |
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