Nitrogen fixation to cyanide at a molybdenum center |
| |
Authors: | Curley John J Cozzolino Anthony F Cummins Christopher C |
| |
Institution: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139-4307, USA. |
| |
Abstract: | Facile methoxymethylation of N(2)-derived nitride NMo(N(t)Bu]Ar)(3) provided the imido cation MeOCH(2)NMo(N(t)Bu]Ar)(3)](+) as its triflate salt in 88% yield. Treatment of the latter with LiN(SiMe(3))(2) provided blue methoxyketimide complex MeO(H)CNMo(N(t)Bu]Ar)(3) in 95% yield. Conversion of the latter to the terminal cyanide complex NCMo(N(t)Bu]Ar)(3), which was the subject of a single-crystal X-ray diffraction study, was accomplished in 51% yield upon treatment with a combination of SnCl(2) and Me(2)NSiMe(3). |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|