Scintillation phase method: A new approach for studying surfactant behavior at liquid/liquid interface |
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Authors: | M G Chernysheva Z A Tyasto G A Badun |
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Institution: | (1) Chemistry Department, Radiochemistry Division, Lomonosov Moscow State University, 1 Leninskie Gory, Moscow, 119991, Russia |
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Abstract: | Radiochemical approach for the investigation of partitioning and adsorption of surfactants at water-oil interfaces has been
developed. The so-called “scintillation phase method” is based on the introduction of tritium labeled surfactant in an aqueous
phase of the water-oil system followed by measuring radioactivity of the whole system. Partition coefficients and the value
of adsorption at water-non-polar liquid interfaces of homologous series of alkyltrimethylammonium bromides (DTAB, TTAB and
CTAB) have been experimentally determined by means of scintillation phase method. The influence of non-ionic surfactants on
TTAB adsorption has also been studied. |
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Keywords: | |
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