Magnetic Fe3O4 nanoparticles supported imine/Thiophene‐nickel (II) complex: A new and highly active heterogeneous catalyst for the synthesis of polyhydroquinolines and 2, 3‐dihydroquinazoline‐4(1H)‐ones |
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Authors: | Lotfi Shiri Leili Heidari Mosstafa Kazemi |
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Affiliation: | Department of Chemistry, Faculty of Basic Sciences, Ilam University, Ilam, Iran |
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Abstract: | A new magnetically separable nickel catalyst (Ni(NO3)2?Imine/Thiophene‐Fe3O4@SiO2) was readily prepared and structurally characterized by Fourier transform infrared spectroscopy (FT‐IR), Scanning electron microscopy (SEM), Energy‐dispersive X‐ray spectroscopy (EDX), Vibrating sample magnetometer (VSM), X‐Ray diffraction (XRD) and Atomic absorption spectroscopy (AAS). The Ni(NO3)2?Imine/Thiophene‐Fe3O4@SiO2 exhibited efficient catalytic activity in the synthesis of 2,3‐dihydroquinazoline‐4(1H)‐ones and polyhydroquinolines. Catalysis research under water and solvent‐free conditions makes also this synthetic protocol ideal and fascinating from the environmental point of view. The catalyst can be magnetically recovered after the reaction and can be reused for many times without appreciable decrease in activity. |
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Keywords: | 2,3‐dihydroquinazoline‐4(1H)‐ones magnetically nickel catalyst magnetically separation polyhydroquinolines solvent‐free condition water |
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