Oxido‐peroxido W(VI)‐histidine–MgAl‐layered double hydroxide composite as an efficient catalyst in sulfide oxidation |
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| Authors: | Mohammad Nikkhoo Mojtaba Amini S Morteza F Farnia Arshad Bayrami Mojtaba Bagherzadeh Sanjeev Gautam Keun Hwa Chae |
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| Institution: | 1. Department of Chemistry, University of Tehran, Tehran, Iran;2. Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, Iran;3. Chemistry Department, Sharif University of Technology, Tehran, Iran;4. Dr. S. S. Bhatnagar University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh, India;5. Advanced Analysis Center, Korea Institute of Science and Technology, Seoul, South Korea |
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| Abstract: | Oxido‐peroxido W(VI)‐histidine–MgAl‐layered double hydroxide composite was prepared by using MgAl‐layered double hydroxide as a host and oxido‐peroxido W(VI)‐histidine complex as a guest. The composite was characterized by XRD, IR, EDX,SEM and TEM techniques. This composite is tested for catalytic selective sulfoxidation reactions using hydrogen peroxide as oxidant showing good to moderate conversion along with high selectivity. |
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| Keywords: | LDH oxidation oxido‐peroxido sulfide tungsten |
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