Denitrogenative Pd/Cu‐catalyzed Suzuki‐type Cross‐coupling of Aryltrifluoroborates with Arylhydrazine Hydrochlorides in Water under Room Temperature |
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| Authors: | Guofang Wang Mengting Meng Liping Deng Kai Cheng Chenze Qi |
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| Institution: | 1. Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing, People's Republic of China;2. Organisch‐Chemisches Institut, Universit?t Heidelberg, Heidelberg, Germany |
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| Abstract: | A water‐soluble palladium‐catalyzed Suzuki‐type cross‐coupling of aryltrifluoroborates with arylhydrazide hydrochlorides was efficiently developed under mild and environmentally benign conditions, in water without any ligand. The newly developed Pd/Cu co‐catalyzed denitrogenative reaction gave a range of structurally diverse substituted biaryls with good to excellent yields, in which the byproduct was nitrogen. |
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| Keywords: | arylhydrazide hydrochlorides aryltrifluoroborates Suzuki‐type cross‐coupling water water‐soluble Pd‐catalyzed |
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