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Synthesis of nanomagnetic supported thiourea–copper(I) catalyst and its application in the synthesis of triazoles and benzamides
Authors:Leila Mohammadi  Mohammad Ali Zolfigol  Ardeshir Khazaei  Meysam Yarie  Samira Ansari  Saeid Azizian  Maryam Khosravi
Affiliation:1. Faculty of Chemistry, Bu‐Ali Sina University, Hamedan, Iran;2. Cinnagen Medical Biotechnology Research Center, Alborz University of Medical Science, Karaj, Iran
Abstract:A novel nanomagnetic supported thiourea–copper(I) complex and inorganic–organic Takemoto‐like hybrid nanomagnetic catalyst was designed, and synthesized. The prepared naomagnetic catalyst was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, energy‐dispersive X‐ray analysis, transmission and scanning electron microscopies, thermogravimetry, nitrogen adsorption/desorption, zeta potential and vibrating sample magnetometry. Furthermore, the fabricated dual‐role inorganic–organic hybrid catalyst shows a striking and robust catalytic activity for the synthesis of triazoles and benzamides through click and coupling reactions, respectively, under mild and eco‐friendly reaction conditions.
Keywords:benzamides  eco‐friendly reaction conditions  nanomagnetic catalyst  thiourea–  copper(I) complex  triazoles
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