Abstract: | The accuracy of Møller–Plesset (MP) perturbation theory and coupled‐cluster (CC) theory can be significantly improved, at essentially no increase in computational cost, by using summation approximants that model the way in which these theories converge to the full configuration interaction limit. Approximants for MP4 and CCSD(T) are presented, their size scaling is analyzed, and the functional analysis of the MP energy, on which the MP4 approximant is based, is discussed. The MP approximants are shown to have a form that is appropriate for describing resonance energies. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2003 |