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Synthese und Kristallstruktur von [N(Hex)4][Cu2(CN)3]
Authors:Thorsten Pretsch  Irene Brüdgam  Hans Hartl
Abstract:Synthesis and Crystal Structure of N(Hex)4] urn:x-wiley:00442313:media:ZAAC200300023:tex2gif-stack-2 Cu2(CN)3] N(Hex)4]urn:x-wiley:00442313:media:ZAAC200300023:tex2gif-stack-3Cu2(CN)3] has been prepared by solvothermal reaction of CuCN with Tetra‐n‐hexylammoniumiodide in acetone. The crystal structure is built up by condensed (CuCN)6 and (CuCN)7 rings, forming a zeolith type cyanocuprate(I) framework urn:x-wiley:00442313:media:ZAAC200300023:tex2gif-stack-4Cu2(CN)3]. Space group R3; α = 44.482(6), c = 21.283(4) Å, V = 36471(9) Å3; Z = 9.
Keywords:Cyanocuprates  Templates  Crystal structure  Zeolith type framework
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