Synthese und Molekülstrukturen von amido‐ und imidoverbrückten Clustern elektronenreicher Übergangsmetalle

Synthesis and Structures of Amido‐ and Imidobridged Clusters of Electron‐rich Transition Metals We report in this article the results, which could be obtained within the DFG‐Project “Nitridobrücken zwischen Übergangsmetallen und Hauptgruppenelementen”. Reactions of electron‐rich transition metal compounds with either stannylated or lithiated amine derivatives lead in the presence of phosphines in different organic solvents to the formation of a large amount of nitrogenbridged transition metal clusters. The structures of 1 — 27 have been characterized by single crystal X‐ray‐structure analysis.