Reaktionen von Cyclostibanen (RSb)n [R = (Me3Si)2CH,n = 3; Me3CCH2, n = 4, 5] mit den Übergangsmetallcarbonyl‐Komplexen [W(CO)5(thf)], [CpxMn(CO)2(thf)], [CpxCr(CO)3]2 und [Co2(CO)8]; Cpx = MeC5H4 |
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| Authors: | G. Bal zs,H. J. Breunig,E. Lork |
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| Affiliation: | G. Balázs,H. J. Breunig,E. Lork |
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| Abstract: | Reactions of Cyclostibanes, (RSb)n [R = (Me3Si)2CH, n = 3; Me3CCH2, n = 4, 5] with the Transition Metal Carbonyl Complexes [W(CO)5(thf)], [CpxMn(CO)2(thf)], [CpxCr(CO)3]2, and [Co2(CO)8]; Cpx = MeC5H4 (RSb)3 [R = (Me3Si)2CH] reacts with [W(CO)5(thf)], [CpxMn(CO)2(thf)], or [Co2(CO)8] to give [(RSb)3W(CO)5] ( 1 ), [RSb{Mn(CO)2Cpx}2] ( 2 ) or [RSbCo(CO)3]2 ( 3 ). The reaction of (R′Sb)n (n = 4, 5; R′ = Me3CCH2) with [CpxCr(CO)3]2 leads to [(R′Sb)4{Cr(CO)2Cpx}2] ( 4 ); Cpx = MeC5H4, thf = Tetrahydrofuran. |
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| Keywords: | Antimony Chromium Tungsten Manganese Cobalt |
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