|
|||||
|
|
Thermochemistry of Heteroatomic Compounds X. The thermochemistry of solution and solvation of substituted alkylphosphonic derivatives |
|
| Authors: | Ovchinnikov V V Sagadeev E V Lapteva L I Khasieva L R Alikberov M Z Sitnikova E Yu Antipin I S Stoikov I I Konovalov A I |
| Institution: | (1) Kazan State Academy of Construction and Architecture, Zelionaya str. 1, Kazan, 420043, Tatrstan;(2) Institute of Organic and Physical Chemistry of Russian Academy of Sciences, Arbusov str. 8, Kazan, 420083, Tatrstan;(3) Kazan State University, Kremiovskaya str. 18, Kazan, 420008, Tatrstan, Russia |
| Abstract: | The enthalpies of vaporization of different classes of phosphorylated alcohols and amines were determined from their enthalpies of solution in hexane and carbon tetrachloride. The enthalpies of specific (hydrogen-bond) interaction with the solvents (chloroform and pyridine) of derivatives containing X-H groups (X=O or N) in the α-position to the P=O group were determined. The results were explained in terms of the spatial structure of such compounds. This revised version was published online in August 2006 with corrections to the Cover Date. |
| Keywords: | enthalpy of solution enthalpy of solvation enthalpy of specific interaction with solvent enthalpy of vaporization phosphonic derivatives |
| 本文献已被 SpringerLink 等数据库收录！ | |