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Catalytic C-H amination with aromatic amines |
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| Authors: | Gephart Raymond T Huang Daria L Aguila Mae Joanne B Schmidt Graham Shahu Andi Warren Timothy H |
| Institution: | Department of Chemistry, Georgetown University, Box 571227, Washington, DC 20057-1227, USA. |
| Abstract: | Aniline joins the club: A β-diketiminato copper(I) catalyst enables C-H amination of anilines employing low catalyst loadings to preclude oxidation to the diazene ArN=NAr. Electron-poor anilines are particularly resistant towards diazene formation and participate in the amination of strong and unactivated C-H bonds. N-alkyl anilines also take part in C-H amination. |
| Keywords: | amination anilines C?H functionalization copper synthetic methods |
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