Kinetics of solid-phase ligand-substitution reactions in diammine(1,4,8,11-Tetraazaundecane)chromium(III) bromide isomers |
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| Authors: | E. A. Pisarev Yu. N. Shevchenko V. A. Logvinenko G. V. Gavrilova |
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| Affiliation: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev;(2) Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk |
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| Abstract: | The kinetics of solid-phase reactions of substitution of coordinated ammonia by outer-sphere bromide ions in [CrL(NH3)2]2Br3·nH2O, where L is 1,4,8,11- tetraazaundecane, n  2–2.5, was studied by a nonisothermal method by differential thermogravimetry, mass spectrometry, and investigations in a flow-type reactor. The kinetic stability of the isomeric salts increases in the series trans
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