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ortho-Alkynylphenyl thioglycosides as a new type of glycosylation donors under the catalysis of Au(I) complexes
Authors:Fei YangQiaoling Wang  Biao Yu
Institution:State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
Abstract:ortho-Alkynylphenyl thioglycosides, prepared readily via Sonagashira coupling of ortho-bromophenyl thioglycosides with alkynes, could undergo glycosidation effectively under the catalysis of a gold(I) complex.
Keywords:Gold(I) catalyst  Glycosylation  Thioglycoside  ortho-Alkynylphenyl thioglycoside  Orthoester
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