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金属间化物(Sm_(1-x)Y_x)_2Fe_(17)N_y中的各向异性机制探讨
引用本文:罗广圣,贺伦燕.金属间化物(Sm_(1-x)Y_x)_2Fe_(17)N_y中的各向异性机制探讨[J].中国稀土学报,1996(2).
作者姓名:罗广圣  贺伦燕
作者单位:南昌大学材料科学与工程系
摘    要:通过X射线衍射和穆斯堡尔谱等手段研究金属间化物(Sm1-xYx)2Fe17Ny中的各向异性产生机制。结果表明,(1)Sm次格子的单轴各向异性较强,对总的各向异性贡献起主导机制;(2)N原子的占位与自旋磁结构密切相关,而与晶体结构无关,N原子的双重占位导致单轴各向异性;(3)Y原子的择优占位导致晶体结构的变化,而对各向异性影响较小。

关 键 词:(Sm_(1-x)Y_x)_2Fe_(17)N_y,各向异性,双重占位,择优占位,穆斯堡尔谱

Study of Anisotropy Mechanism in (Sm_(1-x)Y_x)_2Fe_(17)N_y Intermetallic Compounds
Luo Guangsheng, He Lunyan.Study of Anisotropy Mechanism in (Sm_(1-x)Y_x)_2Fe_(17)N_y Intermetallic Compounds[J].Journal of the Chinese Rare Earth Society,1996(2).
Authors:Luo Guangsheng  He Lunyan
Abstract:The anisotropy mechanism in (Sm1-xYx)2Fe17Ny intermetallic compounds was studied by X-ray diffraction and Mossbauer spectrcacopy methods. The following conclusions were obtained : (1) The uniaxial anisotropy of Sm sublattice is stronger and is the main mechanism of the total anisotropy;(2) The occupiation of N atom is closely concerned with spin magnetic structure and is not related to crystal structure; the double occupiation of N atom leads to the uniaxial anisotropy; (3) The preferential occupiation of Y atom leads to the change of crystal structure and its influence on anisotropy is smaller.
Keywords:Sm_(1-x)Y_x)_2Fe_(17)N_y  Anisotropy  Double occupiation  Preferential occupiation  Mossbauer spectroscopy  
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