| MOLECULAR CHAIN STRUCTURE OF DOPED POLYANILINE |
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| 引用本文： | 景遐斌,唐劲松,王英,雷良才,王宝忱,王佛松. MOLECULAR CHAIN STRUCTURE OF DOPED POLYANILINE[J]. 中国科学B辑(英文版), 1990, 0(7) |
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| 作者姓名： | 景遐斌 唐劲松 王英 雷良才 王宝忱 王佛松 |
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| 作者单位： | Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Polymer Physics Laboratory，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | The chain structure of polyaniline doped with HCl or CF_3COOH has been investigated by FTIR, solid state ~(13)CNMR, resonance laser Raman and UV-VIS spectroscopies. The results show that during the protonic acid doping, a partial redox reaction takes place between the quinone-diimine and benzene-diamine units and it leads to a long conjugate system with a certain charge distribution.
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MOLECULAR CHAIN STRUCTURE OF DOPED POLYANILINE |
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| JING XIA-BIN TANG JIN-SONG WANG YING LEI LIANG-CAI WANG BAO-CHEN WANG FO-SONG. MOLECULAR CHAIN STRUCTURE OF DOPED POLYANILINE[J]. Science in China(Chemistry), 1990, 0(7) |
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| Authors: | JING XIA-BIN TANG JIN-SONG WANG YING LEI LIANG-CAI WANG BAO-CHEN WANG FO-SONG |
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| Abstract: | The chain structure of polyaniline doped with HCl or CF_3COOH has been investigated by FTIR, solid state ~(13)CNMR, resonance laser Raman and UV-VIS spectroscopies. The results show that during the protonic acid doping, a partial redox reaction takes place between the quinone-diimine and benzene-diamine units and it leads to a long conjugate system with a certain charge distribution. |
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| Keywords: | polyaniline protonic acid doping conducting polymers |
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