Water adsorption and desorption on microporous solids at elevated temperature

Summary An accurate gravimetric method was used to explore water adsorption/desorption isotherms between 105 and to 250°C for a number of synthetic and natural porous solids including controlled pore glass, activated carbon fiber monoliths, natural zeolites, pillared clay, and geothermal reservoir rocks. The main goal of this work was to evaluate water adsorption results, in particular temperature dependence of hysteresis, for relatively uniform, nano-structured solids, in the context of other state-of-the-art experimental and modeling methods including nitrogen adsorption, spectroscopy, neutron scattering, and molecular simulation. Since no single method is able to provide a complete characterization of porous materials, a combination of approaches is needed to achieve progress in understanding the fluid-solid interactions on the way to developing a predictive capability.