A new methanol solvate and Hirshfeld analysis of π‐stacking in 2,3,6,7,10,11‐hexahydroxytriphenylene solvates |
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Authors: | Anirban Karmakar Ana E Platero‐Prats Lars
hrstrm |
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Abstract: | The structure of 2,3,6,7,10,11‐hexahydroxytriphenylene (hhtp) methanol monosolvate, C18H12O6·CH3OH, has triclinic symmetry (space group P). The compound has a three‐dimensional layered network structure formed by intermolecular hydrogen bonding. Structure analysis with Hirshfeld surfaces is shown to be a sensitive method for comparing π‐stacking effects in the five known solvates of hhtp. The title structure shows slightly weaker π‐stacking than the dihydrate, but stronger π‐stacking than the other three solvates. |
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