Chlorido[N,N′‐dibenzyl‐N′′‐(trichloroacetyl)phosphoramidato‐κ2O,O′](1,10‐phenanthroline‐κ2N,N′)copper(II) |
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Authors: | Kateryna Gubina Vladimir Ovchynnikov Vladymir Amirkhanov Svetlana Shishkina |
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Abstract: | In the title complex, Cu(C16H16Cl3N3O2P)Cl(C12H8N2)], the CuII cation presents a square‐pyramidal environment, where the CuO2N2 base is formed by two O atoms from carbonyl and phosphoryl groups, and by two N atoms from a 1,10‐phenanthroline molecule. A coordinated Cl atom occupies the apex. N—H...Cl hydrogen bonds link the molecules into one‐dimensional chains. The trichloromethyl group is rotationally disordered over two positions, with occupancies of 0.747 (7) and 0.253 (7). |
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