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Ion-pair induced self-assembly of molecular barrels with encapsulated tetraalkylammonium cations based on a bis-trisurea stave
Authors:Li Shaoguang  Wei Meiying  Huang Xiaojuan  Yang Xiao-Juan  Wu Biao
Affiliation:State Key Laboratory for Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China.
Abstract:A bis-trisurea ligand assembles with the tetraalkylammonium halides to form the flat 'stave' structures or 'barrels' that encapsulate multiple R(4)N(+) guests, depending on the size of the halide anion (Cl(-) or Br(-)) and the R(4)N(+) cation.
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