Direct, enantioselective iridium-catalyzed allylic amination of racemic allylic alcohols |
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| Authors: | Lafrance Marc Roggen Markus Carreira Erick M |
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| Institution: | Laboratorium für Organische Chemie, ETH H?nggerberg, 8093 Zürich (Switzerland) http://www.carreira.ethz.ch |
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| Abstract: | The direct route: Iridium-catalyzed direct conversion of branched allylic alcohols into enantioenriched branched primary allylic amines is highly regio- and enantioselective (see scheme; coe=cyclooctene). |
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| Keywords: | amination direct substitution enantioselectivity iridium sulfamic acid |
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