Solvent-free selective hydrogenation of chloronitrobenzene to chloroaniline over a robust Pt/Fe3O4 catalyst |
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| Authors: | Lian Chao Liu Hongquan Xiao Chao Yang Wen Zhang Kai Liu Yan Wang Yuan |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. |
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| Abstract: | In the absence of solvent, highly selective hydrogenation of o-chloronitrobenzene and m-chloronitrobenzene, with selectivity to the corresponding chloroanilines of ≥99.4% and complete conversion of the substrates, was realized over a robust Pt/Fe(3)O(4) catalyst which was prepared by adsorbing Pt nanoclusters on a Fe(3)O(4) support. |
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