A highly reduced cyanogen ligand derived from cyanide reductive coupling |
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| Authors: | Fox Alexander R Cummins Christopher C |
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| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Room 6-435, Cambridge, MA 02139-4307, USA. |
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| Abstract: | The synthesis, structure, and spectroscopic features of a bimetallic cyanogen complex obtained from the reductive coupling of cyanide by a niobium(IV) precursor are described, and a mechanism for the coupling reaction is proposed based on DFT calculations. |
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