Model systems for flavoenzyme activity. Control of flavin recognition via specific electrostatic interactions |
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| Authors: | Goodman A J Breinlinger E C McIntosh C M Grimaldi L N Rotello V M |
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| Affiliation: | Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA. |
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| Abstract: | [structure: see text] A model system has been used to study the interactions of dipole-containing aromatic systems with oxidized and reduced flavin. Ab initio computational and experimental studies show that dipole orientation within the host is a critical determinant for recognition and redox behavior of the flavin guest. |
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