Group 11 complexes containing the [C5(CN)5]- ligand; 'coordination-analogues' of molecular organometallic systems |
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Authors: | Less Robert J Guan Bihan Muresan Nicoleta M McPartlin Mary Reisner Erwin Wilson Thomas C Wright Dominic S |
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Affiliation: | Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, U.K. rjl1003@cam.ac.uk |
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Abstract: | The reactions of Na[C(5)(CN)(5)] (Na[1]) with group 11 phosphine complexes [(P)(n)MCl] (M = Cu, Ag, Au, P = Ph(3)P; M = Cu, P = dppe (Ph(2)PCH(2)CH(2)PPh(2))] give a range of compounds containing the pentacyanocyclopentadienide ligand, [C(5)(CN)(5)](-) (1). The new complexes [(Ph(3)P)(2)M{1}](2) [M = Cu (3); M = Ag (5)], [(Ph(3)P)(3)Ag{1}] (4), [(dppe)(3)Cu(2){1}(2)] (6) and [Au(PPh(3))(2)][1] (7) include the first complete series of group 11 complexes of any cyclopentadienide ligand to be structurally characterised. |
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