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Catching gaseous SO2 in cone-type lanthanide complexes: an unexpected coordination mode for SO2 in f-element chemistry |
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| Authors: | Benndorf Paul Schmitt Sophia Köppe Ralf Oña-Burgos Pascual Scheurer Andreas Meyer Karsten Roesky Peter W |
| Affiliation: | Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Germany. |
| Abstract: | Easy come, easy go: the first molecular SO(2) complexes of the lanthanides (Ln=Sm, Eu) have been prepared. The compounds can reversibly coordinate gaseous SO(2). Concomitant with the addition and removal of SO(2), the color of the complexes changes reversibly. The structures of the SO(2) compounds could be confirmed in solution and in the solid state. |
| Keywords: | cage compounds coordination compounds lanthanides rare‐earth elements SO2 complexes |
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