Magnesium-catalysed hydroboration of aldehydes and ketones |
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Authors: | Arrowsmith Merle Hadlington Terrance J Hill Michael S Kociok-Köhn Gabriele |
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Institution: | Department of Chemistry, University of Bath, Claverton down, Bath, BA2 7AY, UK. |
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Abstract: | The heteroleptic magnesium alkyl complex CH{C(Me)NAr}(2)Mg(n)Bu] (Ar = 2,6-(i)Pr(2)C(6)H(3)) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane. |
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