活性聚合在星形聚合物合成中的应用

星形聚合物在近年来发展迅速，其结构、形态、合成方法与功能性是高分子科学的研究热点。本文主要从活性离子聚合手段与活性自由基聚合手段两方面对星形聚合物的合成方法进行分类，依托星形聚合物的单体选择、星形臂的特性以及整体功能性进行系统阐述，介绍近年来星形聚合物合成方法、形貌控制以及功能性质的最新研究进展。本文结合现阶段最新的研究成果，对星形聚合物在功能与应用之间的广泛前景与联系进行了展望与预测。

Living/Controlled Polymerization in the Synthesis of Star Polymer

The study on star polymers developed so rapidly in recent years. The research of structure, architecture, synthesis methodology, and function has become a hotspot in polymer and biomacromolecules field. In this paper, synthesis of star polymers is classified on living ion polymerization and living/controlled radical polymerization. The monomer choosing strategy, characteristic of the star polymers’ arms, and the functionality of star polymers are generally discussed. The recent progress of synthesis, architecture, construction, function and character of star polymers are introduced. Based on the recent progress, the relationship between the function and application of star polymers is prospected.