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Photoelectron spectra of bicyclic peroxides |
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| Authors: | Rolf Gleiter Peter Schang Waldemar Adam Henny J Eggelte Ihsan Erden AJohn Bloodworth |
| Institution: | Organisch-Chemisches Institut der Universität Heidelberg, D-6900 Heidelberg W. Germany;Institut für Organische Chemie der Technischen Hochschule Darmstadt, D-6100 Darmstadt W. Germany;Department of Chemistry, University of Puerto Rico, Rio Piedras 00931 Puerto Rico;Department of Chemistry, University College London, London WC1H 0AJ Great Britain |
| Abstract: | The He(I) photoelectron spectra of nine bicyclic alkyl peroxide have been recorded. The first peaks are assigned by comparison with results of a MINDO/3 calculation. A correlation between the split of the first two ionization potentials and the OO torsional angle Θ is found. |
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