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Influence of temperature on ultrasonic velocity measurements of ethanol+water+1-propanol mixtures
Authors:J M Resa  C González  J M Goenaga  M Iglesias
Institution:1.Departamento de Ingeniería Química,Universidad del Pais Vasco,Vitoria,Spain;2.Departament d’Enginyeria Química, Escola Tècnica Superior d’Enginyeria Química,Universitat Rovira i Virgili,Tarragona,Spain
Abstract:The ultrasonic velocity of the ternary mixtures ethanol+water+1-propanol at the range 288.15–323.15 K and atmospheric pressure, has been measured over the whole concentration range. The corresponding change of isentropic compressibility was computed from the experimental data. The results were fitted by means of a temperature dependent equation, such parameters being gathered. The obtained experimental values indicate varying extent of interstitial accommodation among unlike molecules as a function of steric hindrance attending to 1-propanol composition as key component and as a function of hydrogen bond and temperature attending to ethanol composition as key component.
Keywords:derived magnitude  estimation  ethanol+water+1-propanol  isentropic compressibilities  mixtures  ultrasonic velocities
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