Borylation of α-hydroxyalkylphosphine oxides in the presence of strong bases |
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| Authors: | G N Nikonov T V Vasyanina |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Lithium (sodium) 2,2,5-triphenyl-5-oxo-1,3,2,5-dioxaborataphosphorinanes, forming crystals with two molecules of water, are produced when bis(hydroxymethyl)phenylphosphine oxide is reacted with isobutyl diphenylborate in the presence of metallic sodium or lithium (sodium) alcoholate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 886–890, April, 1990. |
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