Synthesis of asymmetrically substituted 1,4,7,10-tetraazacyclododecanes for the triggered near infrared emission from lanthanide complexes |
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| Authors: | Borbas K Eszter Bruce James I |
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| Institution: | Department of Chemistry, The Open University, Milton Keynes, UK MK7 6AA. |
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| Abstract: | A synthetic strategy to prepare asymmetrically substituted 1,4,7,10-tetrazadodecane derivatives was developed to prepare a novel series of photoactive donor-acceptor quencher triads based on Yb and Nd complexes; a nucleoside quencher is used to regulate the extent of energy transfer between the donor and the acceptor. |
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