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Evidence of four light-induced metastable states in iron-nitrosyl complexes |
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| Authors: | D Schaniel Th Woike M Imlau |
| Institution: | a Institut für Mineralogie und Geochemie, Universität zu Köln, Zülpicherstr. 49b, 50674 Köln, Germany b Department of Nuclear Engineering, Sofia University, Boul. J. Bourchier 5, 1164 Sofia, Bulgaria c Fachbereich Physik, Universität Osnabrück, Barbarastr. 7, 49069 Osnabrück, Germany |
| Abstract: | Thermodynamic measurements on irradiated Na2Fe(CN)5NO]⋅ 2H2O reveal the existence of four light-induced long-lived metastable states, which decay exponentially in time. The activation energies and frequency factors of the four independent states are determined from isothermal calorimetric and differential scanning calorimetric measurements. |
| Keywords: | 64 60 My 65 40 Gr 65 40 b 05 70 _method=retrieve& _eid=1-s2 0-S0040603104005167& _mathId=si2 gif& _pii=S0040603104005167& _issn=00406031& _acct=C000054348& _version=1& _userid=3837164& md5=37a348707ae76882f845d694960d7108')" style="cursor:pointer &minus" target="_blank">" alt="Click to view the MathML source" title="Click to view the MathML source">&minus a |
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