Mechanism of the formation of porous silicate mesophases |
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Authors: | V. N. Romannikov V. B. Fenelonov A. V. Nosov A. Yu. Derevyankin S. V. Tsybulya V. N. Kolomiichuk |
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Affiliation: | (1) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090 Novosibirsk, Russia |
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Abstract: | The formation of mesoporous mesophase systems prepared by precipitation of soluble forms of SiO2 at the surface of micelles of cetyltrimethylammonium cations was examined. A molecular mechanism of the formation of a silicate coating and a macroscopic mechanism of the formation of a mesophase were found and discussed. A combination of these mechanisms describes the processes proceeding during the synthesis. It can also explain the observed changes in the structure and texture characteristics of the mesophase. |
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